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Perkin Transactions 2 1972-2002 logo

Year 1981
Main Index

Issue 1


Front cover

pg X001; DOI:
10.1039/P298100FX001
PDF
Contents pages

pg P001; DOI:
10.1039/P298100FP001
PDF
The crystal structure of 1,4,7,14,17,20,28,35-octaoxa[2.23,29][7.718,34]-orthocyclophane and its multihydrated complex with potassium chloride
Ian R. Hanson and Mary R. Truter
pg 1; DOI:
10.1039/P29810000001
PDF
Back cover

pg X003; DOI:
10.1039/P298100BX003
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Crystal structure of two bridged macrobicyclic polyethers, 1,5,12,16,23,26,29-heptaoxa[7][5.5]orthocyclophane and 1,5,12,16,23,26,29,32-octaoxa[10][5.5]orthocyclophane
John D. Owen
pg 12; DOI:
10.1039/P29810000012
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Bicyclic phosphanes: synthesis, stereochemistry, and conformation
Corine Bonningue Douraid Houalla Michel Sanchez Robert Wolf and Fayez H. Osman
pg 19; DOI:
10.1039/P29810000019
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The synthesis of 1,4-disubstituted bicyclo[2.2.2]octanes exhibiting wide-range, enantiotropic nematic phases
George W. Gray and Stephen M. Kelly
pg 26; DOI:
10.1039/P29810000026
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Electrophilic substitution with rearrangement. Part 9. Dienones derived from brominations of o-, m-, and p-cresol
Judith M. Brittain Peter B. D. de la Mare and Paul A. Newman
pg 32; DOI:
10.1039/P29810000032
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Naphthalene tetrachlorides and related compounds. Part 9. Structures and reactions of some 2-methylnaphthalene tetrachlorides
Peter B. D. de la Mare and Bernice C. J. McKellar
pg 42; DOI:
10.1039/P29810000042
PDF
Perchlorate esters. Part 3. Correlation of the rates of reaction of arenesulphonate ions with methyl perchlorate in acetonitrile
Dennis N. Kevill Gloria Meichia L. Lin and Mohd S. Bahari
pg 49; DOI:
10.1039/P29810000049
PDF
Photolysis and thermolysis of 3-n-butyl-3-phenyldiazirine
Michael T. H. Liu Glenn E. Palmer and Najmul H. Chishti
pg 53; DOI:
10.1039/P29810000053
PDF
1,8-Diacetylnaphthalene and its cyclisation to 3-methyl-1H-phenalen-1-one
Beverly M. Davis Peter H. Gore Kenneth A. K. Lott Eric L. Short and Hakim G. Shinouda
pg 58; DOI:
10.1039/P29810000058
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Protonation of alkyl aryl sulphides in antimony pentafluoride–fluorosulphonic acid solution
Mirjana Eckert-Maksi
pg 62; DOI:
10.1039/P29810000062
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General acid inhibition and the absence of deuterium isotope exchange in base catalysed hydrolysis of 2,4-dinitrophenyl arylmethanesulphonate esters in aqueous solution
Sergio Thea Nasrin Kashefi-Naini and Andrew Williams
pg 65; DOI:
10.1039/P29810000065
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The effect of changing the substituent in the sulphonyl group in base catalysed hydrolysis of 2,4-dinitrophenyl arylmethanesulphonate esters in aqueous solution
Sergio Thea and Andrew Williams
pg 72; DOI:
10.1039/P29810000072
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The effect of structure change in bases on their reaction with 2,4-dinitrophenyl arylmethanesulphonate esters in water
Sergio Thea M. Ghazali Harun Nasrin Kashefi-Naini and Andrew Williams
pg 78; DOI:
10.1039/P29810000078
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Intramolecular hydrogen bonding and molecular conformations of nucleosides: uridine derivatives
Danuta Plochocka Andrzej Rabczenko and David B. Davies
pg 82; DOI:
10.1039/P29810000082
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Carbon-13 nuclear magnetic resonance spectra of 3,7-disubstituted bicyclo[3.3.1]nonanes: conformation and through-space interaction
Yasuhisa Senda Jun-ichi Ishiyama and Shin Imaizumi
pg 90; DOI:
10.1039/P29810000090
PDF
Nitration in aqueous nitric acid: the rate profile and the limiting reaction rates
Mark R. Draper and John H. Ridd
pg 94; DOI:
10.1039/P29810000094
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Methanolysis (solvolysis) and synthesis of 4-substituted 4-benzyloxybenzyl chlorides and some related compounds: comparisons with the corresponding benzoyl compounds
Jorge Armando Luis Jorge Nilo Zengo Kiyan Yukino Miyata and Joseph Miller
pg 100; DOI:
10.1039/P29810000100
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Statistical analysis of solvatochromic shift data
Michael Sjöström and Svante Wold
pg 104; DOI:
10.1039/P29810000104
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Orientation in photochemical substitution of phenyl and methyl radicals in toluene: MO calculation
Yoshiro Ogata Kohtaro Tomizawa Kyoji Furuta and Hiroshi Kato
pg 110; DOI:
10.1039/P29810000110
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Elimination and hydrolysis reactions of 4-alkoxyimino-5,6-dihydro-6-alkoxyaminopyrimidin-2(1H)-ones and 4-alkoxyimino-5-fluoro-5,6-dihydro-6-alkoxyaminopyrimidin-2(1H)-ones in strong acid media
David J. Palling Peter M. Schalke Paul J. Atkins and C. Dennis Hall
pg 113; DOI:
10.1039/P29810000113
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Ring-opening reactions of some 1-ethoxycarbonylaziridines with acetic acid in cyclohexane
Hiroshi Takeuchi and Kikuhiko Koyama
pg 121; DOI:
10.1039/P29810000121
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Conformation and photoelectron spectra of 2-(2-furyl)pyrrole and 2-(2-thienyl)pyrrole
Vinicio Galasso Leo Klasinc Aleksendar Sablji Nenad Trinajsti Giuseppe C. Pappalardo and Wolfgang Steglich
pg 127; DOI:
10.1039/P29810000127
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The acid-catalysed hydrolysis of episulphoxides
Azhari Saleh and John G. Tillett
pg 132; DOI:
10.1039/P29810000132
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The influence of remote substituents on amide bond formation. The reaction of oxazolinones with benzylamine
David J. Phelps Paul V. Godreau and Everton S. Nicholas
pg 140; DOI:
10.1039/P29810000140
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Reactions of 1,1-dialkoxyalkene radical cations in aqueous solution with OH, HPO42–, and H2O. Electron spin resonance spectroscopic, pulse conductometric, and product analytical studies
Günter Behrens Eberhard Bothe Günther Koltzenburg and Dietrich Schulte-Frohlinde
pg 143; DOI:
10.1039/P29810000143
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Crystal and molecular structures of butan-2-one p-nitrophenylhydrazone (1), propanal 2,4-dinitrophenylhydrazone (2), dimethyl 2-oxo-propanedioate phenylhydrazone (3), and dimethyl 2-oxopropanedioate 2,4-dinitrophenylhydrazone (4): hydrogen bonding and bond order in phenylhydrazones
(the late) Brian Vickery Gerald R. Willey and Michael G. B. Drew
pg 155; DOI:
10.1039/P29810000155
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An electron spin resonance study of alkyl radical addition to diethyl vinylphosphonate
Jehan A. Baban and Brian P. Roberts
pg 161; DOI:
10.1039/P29810000161
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The crystal and molecular structure of R-(–)-1,1-binaphthyl: the conformational isomerism and a comparison of the chiral with the racemic packing mode
Reiko Kuroda and Stephen F. Mason
pg 167; DOI:
10.1039/P29810000167
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Leaving group effects in thiolester hydrolysis. Part 2. On the possibility of an elimination–addition (keten) mediated pathway in S-acetylcoenzyme a basic hydrolysis and acetyl transfer
Kenneth T. Douglas Norbert F. Yaggi and Cynthia M. Mervis
pg 171; DOI:
10.1039/P29810000171
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Barriers to intramolecular hydride transfers in some polycyclic hydroxyketones
Gabrielle-Anne Craze and Ian Watt
pg 175; DOI:
10.1039/P29810000175
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Radiation mechanisms. Part 21. Electron spin resonance studies of the effect of ionising radiation on halogenobenzenes: the formation of * anions and ipso addition radicals
Shuddhodan Prasad Mishra and Martyn C. R. Symons
pg 185; DOI:
10.1039/P29810000185
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A kinetic study of the mechanisms of SNAr reactions of neutral and cationic metal-complexed halogenoarenes with methoxide ion
Anthony C. Knipe Samuel J. McGuinness and William E. Watts
pg 193; DOI:
10.1039/P29810000193
PDF
Assignment of the carbon-13 spectrum of vancomycin and its derivatives
Alessandro Bongini James Feeney Michael P. Williamson and Dudley H. Williams
pg 201; DOI:
10.1039/P29810000201
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Electron spin resonance studies. Part 59. Radical reactions of thiophens: the formation and reactions of some sulphur-conjugated radical-cations
Bruce C. Gilbert Richard O. C. Norman and Peter S. Williams
pg 207; DOI:
10.1039/P29810000207
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synanti-Photoisomerisation of chelated arylhydrazones of 1,2,3-triketones: a correction
Pierre Courtot Roger Pichon and Jacques Le Saint
pg 219; DOI:
10.1039/P29810000219
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Issue 2


Front cover

pg X005; DOI:
10.1039/P298100FX005
PDF
Contents pages

pg P005; DOI:
10.1039/P298100FP005
PDF
Back cover

pg X007; DOI:
10.1039/P298100BX007
PDF
Nucleophilic substitution at sulphonyl sulphur. Part 1. Reactivity of thiophen-2-sulphonyl halides in water and methanol–acetonitrile
Antonino Arcoria Francesco P. Ballistreri Giuseppe Musumarra and Gaetano A. Tomaselli
pg 221; DOI:
10.1039/P29810000221
PDF
Conformational behaviour of organic carbonyl compounds. Part 2. Aldehydes and acetyl derivatives of condensed aromatic hydrocarbons
Rois Benassi Dario Iarossi Ugo Folli Luisa Schenetti and Ferdinando Taddei
pg 228; DOI:
10.1039/P29810000228
PDF
Solid-state transformations and crystal structure analysis of - and -o-acetamidobenzamide
Lou A. Errede Margaret C. Etter Robert C. Williams and Stephen M. Darnauer
pg 233; DOI:
10.1039/P29810000233
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Reactions of N-heteroaromatic bases with nitrous acid. Part 6. Kinetics of the nitrosation of 2- and 4-methylaminopyridine and their 1-oxide derivatives
Evangelos Kalatzis and Panayiotis Papadopoulos
pg 239; DOI:
10.1039/P29810000239
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Reactions of N-heteroaromatic bases with nitrous acid. Part 7. Kinetics of the nitrosation of secondary and of the diazotisation of primary -aminopyridines
Evangelos Kalatzis and Panayiotis Papadopoulos
pg 248; DOI:
10.1039/P29810000248
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Aromatic C-nitroso compounds. Thermodynamics and kinetics of the equilibrium between 2,6-dimethylnitrosobenzene and its trans-dimer
Michel Azoulay Richard Lippman and Gunnar Wettermark
pg 256; DOI:
10.1039/P29810000256
PDF
Functional micellar catalysis. Part 4. Catalysis of activated ester hydrolysis by surfactant systems as chymotrypsin models
Lucio Anoardi Roberto Fornasier and Umberto Tonellato
pg 260; DOI:
10.1039/P29810000260
PDF
The crystal and molecular structure of 1,2,3,5-tetramethylbenzo[b]thiophenium tetrafluoroborate and some theoretical calculations on the hypothetical 1H-thiophenium cation
R. Morrin Acheson Richard J. Prince Garry Procter John D. Wallis and David J. Watkin
pg 266; DOI:
10.1039/P29810000266
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Electronic spectra and electronic structures of ketenimines and carbodiimides
Wolfgang Kosbahn and Wolfgang Runge
pg 270; DOI:
10.1039/P29810000270
PDF
Dipole moment and helium(I) photoelectron spectroscopic studies of the conformation of di-2-pyridyl and diphenyl dichalcogenides R2X2(X = S, Se, or Te)
Francesco P. Colonna Giuseppe Distefano Vinicio Galasso Kurt J. Irgolic Giuseppe C. Pappalardo and Leslie Pope
pg 281; DOI:
10.1039/P29810000281
PDF
Electrophilic substitution in naphthalenes: cyclisation of naphthylbutanols to tetrahydrophenanthrene
Anthony H. Jackson Patrick V. R. Shannon and Paul W. Taylor
pg 286; DOI:
10.1039/P29810000286
PDF
Kinetics and mechanisms of the Bamberger rearrangement. Part 3. Rearrangement of phenylhydroxylamines to p-aminophenols in aqueous sulphuric acid solutions
Takaaki Sone Yuuji Tokuda Toshimi Sakai Seiji Shinkai and Osamu Manabe
pg 298; DOI:
10.1039/P29810000298
PDF
The effect of salt formation on the molecular structure and charge distribution in imines: the crystal and molecular structures and the ultraviolet, infrared, and the 1H and 13C nuclear magnetic resonance spectra of 2,6-dimethyl-4-(p-nitrophenylimino)pyran and its hydrobromide and methobromide salts
Michael P. Sammes Richard L. Harlow and Stanley H. Simonsen
pg 303; DOI:
10.1039/P29810000303
PDF
Mechanistic studies in the chemistry of urea. Part 8. Reactions of urea, 1-methylurea, and 1,3-dimethylurea with some acyloins and butane-2,3-dione (diacetyl) in acid solution
Anthony R. Butler and Ishtiaq Hussain
pg 310; DOI:
10.1039/P29810000310
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Mechanistic studies in the chemistry of urea. Part 9. Reactions of 1,2-diaminoethane and related compounds with urea and N-alkylated ureas
Anthony R. Butler and Ishtiaq Hussain
pg 317; DOI:
10.1039/P29810000317
PDF
Mechanistic studies in the chemistry of urea. Part 10. Reaction of urea and 1,3-dimethylurea with cyclohexane-1,2-dione and of imidazolidin-2-one (ethyleneurea) with several -diketones
Anthony R. Butler Ishtiaq Hussain and Kathleen M. Peet
pg 320; DOI:
10.1039/P29810000320
PDF
Isomerization of cis-1,2-diarylethylenes. Catalysis by selenium, methanesulphonic acid, and potassium t-butoxide
Emanuele Maccarone Antonino Mamo Giancarlo Perrini and Michele Torre
pg 324; DOI:
10.1039/P29810000324
PDF
Nucleophilicity of phenolates in the reaction with p-nitrophenyl acetate in ethanol
Giuseppe Guanti Giorgio Cevasco Sergio Thea Carlo Dell'Erba and Giovanni Petrillo
pg 327; DOI:
10.1039/P29810000327
PDF
The crystal structures of a macrocycle containing 2,6-pyridino and piperazino subunits and of the tetrachlorocobaltate(II) salt of its diprotonated cation
Frank R. Fronczek Veronica K. Majestic George R. Newkome William E. Hunter and Jerry L. Atwood
pg 331; DOI:
10.1039/P29810000331
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The effect of electrochemically generated positive bromine species in acetonitrile on the cleavage of C–Br and C–Cl bonds
James Y. Becker and Dvora Zemach
pg 336; DOI:
10.1039/P29810000336
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Photochromic heterocyclic fulgides. Part 3. The use of (E)--(2,5-dimethyl-3-furylethylidene)(isopropylidene)succinic anhydride as a simple convenient chemical actinometer
Harry G. Heller and John R. Langan
pg 341; DOI:
10.1039/P29810000341
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Polarography of some arylazothiohydantoin derivatives
S. Darwish H. M. Fahmy M. A. Abdel Aziz and A. A. El Maghraby
pg 344; DOI:
10.1039/P29810000344
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Diastereoisomeric charge-transfer complexes. Measurement of thermodynamic constants by 1H nuclear magnetic resonance spectroscopy
Ayala Balan and Hugo E. Gottlieb
pg 350; DOI:
10.1039/P29810000350
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Linear solvation energy relationship. Part 11. An analysis of nitrogen-15 solvent shifts in amides
Mortimer J. Kamlet Charles Dickinson and Robert W. Taft
pg 353; DOI:
10.1039/P29810000353
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On the mechanism of the action of thermolysin: kinetic study of the thermolysin-catalysed condensation reaction of N-benzyloxycarbonyl-L-aspartic acid with L-phenylalanine methyl ester
Kiyotaka Oyama Kei-ichi Kihara and Yuji Nonaka
pg 356; DOI:
10.1039/P29810000356
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Catalysis of N-nitrosation and diazotisation by thiourea and thiocyanate ion
Thomas A. Meyer and D. Lyn H. Williams
pg 361; DOI:
10.1039/P29810000361
PDF
Enthalpies of solution of 2,2-bipyridyl, 1,10-phenanthroline, and 1,10-phenanthroline monohydrate
John Burgess and Robert Sherry
pg 366; DOI:
10.1039/P29810000366
PDF
The characterisation of 1,1-diphenylstannacyclopentane and 1,1,6,6-tetraphenyl-1,6-distannacyclodecane. An X-ray diffraction study of the distannacyclodecane
Alwyn G. Davies Man-Wing Tse John D. Kennedy William McFarlane Geoffrey S. Pyne Mark F. C. Ladd and David C. Povey
pg 369; DOI:
10.1039/P29810000369
PDF
The Friedel–Crafts acetylation of naphthalene. Evidence for concurrent second- and third-order reactions
Andreas D. Andreou Roger V. Bulbulian Peter H. Gore Fadhil S. Kamounah Adhid Y. Miri and David N. Waters
pg 376; DOI:
10.1039/P29810000376
PDF
Electron spin resonance studies of spin trapping. On the role of hydroxylamines and an oxaziridine in the formation of nitroxides following addition of hydroxyalkyl radicals to N-t-butyl--phenylnitrone
James M. Coxon Bruce C. Gilbert and Richard O. C. Norman
pg 379; DOI:
10.1039/P29810000379
PDF
Oxidation of organic sulphides by chlorine and iodosylbenzene diacetate: kinetics and mechanism
Alan A. Humffray and Helmut E. Imberger
pg 382; DOI:
10.1039/P29810000382
PDF
Linear free energy relationships in the thiophen series. Part 2. The kinetics of the reactions of some 2-bromo-3-nitro-5-X-thiophens with substituted anilines in methanol
Giovanni Consiglio Caterina Arnone Domenico Spinelli Renato Noto and Vincenzo Frenna
pg 388; DOI:
10.1039/P29810000388
PDF
Thermal and photochemical reactions of organocobaloximes with diphenyl disulphide and diphenyl diselenide
Jean Deniau Kiem N. V. Duong Alain Gaudemer Peter Bougeard and Michael D. Johnson
pg 393; DOI:
10.1039/P29810000393
PDF
The kinetics of the reaction of phenyl 2,4,6-trinitrophenyl ether with aniline in methanol, acetonitrile, tetrahydrofuran, ethyl acetate, and benzene
Olayinka Banjoko and Paul Otiono
pg 399; DOI:
10.1039/P29810000399
PDF
The 13C nuclear magnetic resonance substituent chemical shifts of 2-substituted indenes. Interpretation by a multivariate data analysis method
Bertil Eliasson and Ulf Edlund
pg 403; DOI:
10.1039/P29810000403
PDF
Pyridine nitrogen reactivity
C. David Johnson Ian Roberts and Peter G. Taylor
pg 409; DOI:
10.1039/P29810000409
PDF
Reaction of NN-dimethylimidazolidine-2-thione with methyl iodide. Kinetic and thermodynamic aspects
Yasuhiko Kondo Tetsuya Yamada and Shigekazu Kusabayashi
pg 414; DOI:
10.1039/P29810000414
PDF
Autoxidation of alkyl compounds of zirconium and hafnium
Peter B. Brindley and Martin J. Scotton
pg 419; DOI:
10.1039/P29810000419
PDF

Issue 3


Front cover

pg X009; DOI:
10.1039/P298100FX009
PDF
Contents pages

pg P009; DOI:
10.1039/P298100FP009
PDF
Back cover

pg X011; DOI:
10.1039/P298100BX011
PDF
Electron spin resonance and molecular orbital study of radicals in irradiated fluoro-derivatives
A. Faucitano A. Buttafava F. Faucitano Martinotti G. Caporiccio and C. Corti
pg 425; DOI:
10.1039/P29810000425
PDF
Enhanced reactivities in substitution and elimination reactions in dimethyl sulphoximide
Naomichi Furukawa Fujio Takahashi Toshiaki Yoshimura Hiroyuki Morita and Shigeru Oae
pg 432; DOI:
10.1039/P29810000432
PDF
Nucleophilic substitution at sulphonyl sulphur. Part 2. Hydrolysis and alcoholysis of aromatic sulphonyl chlorides
Francesco P. Ballistreri Alfio Cantone Emanuele Maccarone Gaetano A. Tomaselli and Mario Tripolone
pg 438; DOI:
10.1039/P29810000438
PDF
Carbonyl n* absorption enhancement in -phenylketones: the molecular geometry of the 6-benzyl-2,6-dimethylcyclohexa-2,4-dienone Diels–Alder dimer and its photocage product
Hans-Dieter Becker Brian W. Skelton and Allan H. White
pg 442; DOI:
10.1039/P29810000442
PDF
Analysis of the dependence of acid dissociation constants on temperature
Michael J. Blandamer John W. M. Scott and Ross E. Robertson
pg 447; DOI:
10.1039/P29810000447
PDF
Cope interconversions of the 9-methoxy-endo-tricyclo[4.2.1.0]nona-3,7-dienyl cation and its [4.3.0.0]tautomer. Evidence of enhanced ionic stability by delocalization of neighbouring bonds
Pieter Schipper Jan W. de Haan and Henk M. Buck
pg 457; DOI:
10.1039/P29810000457
PDF
Thermochemical bond dissociation energies of carbon–magnesium bonds
Torkil Holm
pg 464; DOI:
10.1039/P29810000464
PDF
Reaction of 4,6-O-benzylideneglycals with benzoic acid, triphenyl-phosphine, and diethyl azodicarboxylate and of the products with sodium methoxide. X-Ray structure of 1-O-benzoyl-4,6-O-benzylidene-2-deoxy-3-O-methyl--D-arabino-hexopyranose, C21H22O6
R. D. Guthrie Robert W. Irvine Bruce E. Davison Kim Henrick and Jill Trotter
pg 468; DOI:
10.1039/P29810000468
PDF
Studies on the mechanism of the enolization reaction of Grignard reagents and ketones. Part 2. Pseudo-first-order rate and deuterium isotope effect studies
A. George Pinkus and Arunachalam Sabesan
pg 473; DOI:
10.1039/P29810000473
PDF
Crystal structure of 5,6-didehydrodibenzo[a,e]cyclo-octene
Rudolf A. G. de Graaff Sybout Gorter Cornelius Romers Henry N. C. Wong and Franz Sondheimer
pg 478; DOI:
10.1039/P29810000478
PDF
First thermodynamic dissociation constants of barbituric acid derivatives in water at 25 C. Part 3. 5,5-Alkylenebarbituric acid derivatives. A comparison with 5,5-dialkylbarbituric acids, and with mono- and di-carboxylic acids
Robert H. McKeown and Richard J. Prankerd
pg 481; DOI:
10.1039/P29810000481
PDF
A theoretical investigation of the energy and structure of ion–molecule pairs in polar solvents. Part 2. Methanediazonium cation in water
Pierfranco Demontis Roberta Ercoli Aldo Gamba Giuseppe B. Suffritti and Massimo Simonetta
pg 488; DOI:
10.1039/P29810000488
PDF
Conformational analysis of 2- and 3-phosphoglyceric acids by 1H and 13C nuclear magnetic resonance spectroscopy
Eirian H. Curzon Geoffrey E. Hawkes Edward W. Randall H. G. Britton and G. Victor Fazakerley
pg 494; DOI:
10.1039/P29810000494
PDF
The separation of polar and steric effects. Part 14. Kinetics of the reactions of benzoic acid and of ortho-substituted benzoic acids with diazodiphenylmethane in various alcohols
M. Hanif Aslam Alan G. Burden Norman B. Chapman John Shorter and Marvin Charton
pg 500; DOI:
10.1039/P29810000500
PDF
The mechanism for interconversion of stereoisomers in N-(2,3-dihydro-2-oxobenzoxazol-3-yl)- and N-(1,2-dihydro-2-oxoquinolin-1-yl)-N-1-methylallylarenesulphenamides
Robert S. Atkinson and Brian D. Judkins
pg 509; DOI:
10.1039/P29810000509
PDF
Non-supported and resin-supported oligo(oxyethylenes) as solid–liquid phase-transfer catalysts. Effect of chain length and head-group
James G. Heffernan William M. MacKenzie and David C. Sherrington
pg 514; DOI:
10.1039/P29810000514
PDF
ipso-Attack in the nitration of aromatic amines. Part 1. The reactions of NN-dimethyl-p-toluidine and some related compounds
Fatima Al-Omran Kenji Fujiwara Janet C. Giffney John H. Ridd and Stephen R. Robinson
pg 518; DOI:
10.1039/P29810000518
PDF
The stabilities of Meisenheimer complexes. Part 24. Some reactions of 2,4,6-trinitrotoluene and 2,4,6-trinitrobenzyl chloride with bases
David N. Brooke Michael R. Crampton George C. Corfield Peter Golding and Gerard F. Hayes
pg 526; DOI:
10.1039/P29810000526
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The stabilities of Meisenheimer complexes. Part 25. Kinetic studies of the reaction of 1,3,5-trinitrobenzene with aliphatic amines in dimethyl sulphoxide
Michael R. Crampton and Brenda Gibson
pg 533; DOI:
10.1039/P29810000533
PDF
The conformation of 4-acetylpyridine determined from proton and deuterium nuclear magnetic resonance spectra of a nematic phase
James W. Emsley Marcello Longeri and Angelo Liguori
pg 540; DOI:
10.1039/P29810000540
PDF
Selectivity in the halogenation of hexane by tertiary aminium radicals from the photodecomposition of N-halogenoammonium perchlorates
Steven E. Fuller John R. Lindsay Smith Richard O. C. Norman and Raymond Higgins
pg 545; DOI:
10.1039/P29810000545
PDF
An electron spin resonance study of pentenynyl and pentadiynyl radicals
Charles Roberts and John C. Walton
pg 553; DOI:
10.1039/P29810000553
PDF
Vibrational spectroscopy and conformations of 2-alkoxycarbonyl-3-aminoacrylic esters
Antonio Gómez-Sanchez Eugenia Sempere and Juana Bellanato
pg 561; DOI:
10.1039/P29810000561
PDF
Kinetics and mechanism of the reactions of primary amines with pyrylium cations
Alan R. Katritzky and Ruben H. Manzo
pg 571; DOI:
10.1039/P29810000571
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Structural studies of some hydroxyeriobrucinol derivatives
Emilio L. Ghisalberti Philip R. Jefferies Colin L. Raston Brian W. Skelton Allan H. White and Graeme K. Worth
pg 576; DOI:
10.1039/P29810000576
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Structural studies in the bruceol system
Emilio L. Ghisalberti Philip R. Jefferies Colin L. Raston Brian W. Skelton Alan D. Stuart and Allan H. White
pg 583; DOI:
10.1039/P29810000583
PDF
Stepwise proton transfer in the acid-catalysed hydrolysis of 3,1-benzoxazin-4-ones: electrostatic or hydrogen-bond stabilisation of the conjugate acid
A. Peter D'Rozario Derek J. Greig Rober F. Hudson and Andrew Williams
pg 590; DOI:
10.1039/P29810000590
PDF

Issue 4


Front cover

pg X013; DOI:
10.1039/P298100FX013
PDF
Contents pages

pg P013; DOI:
10.1039/P298100FP013
PDF
Back cover

pg X015; DOI:
10.1039/P298100BX015
PDF
Stereochemistry of addition to the carbonyl group. Part 17. Study of the factors affecting asymmetric induction in condensation reactions of methyl- and phenyl-magnesium bromide with chiral carbonyl compounds
Odon Arjona Rafael Pérez-Ossorio Alfredo Pérez-Rubalcaba and Maria L. Quiroga
pg 597; DOI:
10.1039/P29810000597
PDF
Conformational studies by dynamic nuclear magnetic resonance. Part 20. Internal motion in hydrazones and related derivatives
Lodovico Lunazzi and Dante Macciantelli
pg 604; DOI:
10.1039/P29810000604
PDF
The thermal elimination of iodine from some substituted -iodonaphthalenes: a structural study
Donald W. Cameron Geoffrey I. Feutrill Linda J. H. Pannan Colin L. Raston Brian W. Skelton and Allan H. White
pg 610; DOI:
10.1039/P29810000610
PDF
Electrophilic ipso-substitutions. Part 1. Reaction of 3-substituted indoles with nitronium and nitrosonium ions
Martino Colonna Lucedio Greci and Marino Poloni
pg 628; DOI:
10.1039/P29810000628
PDF
An electron spin resonance study of pentadienyl and related radicals: homolytic fission of cyclobut-2-enylmethyl radicals
Alwyn G. Davies David Griller Keith U. Ingold David A. Lindsay and John C. Walton
pg 633; DOI:
10.1039/P29810000633
PDF
Catalysis in aromatic nucleophilic substitution. Part 5. Reactions of piperidine with methyl 2-methoxy-3-nitrothiophen-5-carboxylate and 5-acetyl-2-methoxy-3-nitrothiophen
Giovanni Consiglio Caterina Arnone Domenico Spinelli and Renato Noto
pg 642; DOI:
10.1039/P29810000642
PDF
The polarisation and charge-transfer (PCT) theoretical model for the prediction and the interpretation of the relationship between reactivity and selectivity
Martin Godfrey
pg 645; DOI:
10.1039/P29810000645
PDF
An electron spin resonance study on the interactions between bis-(pentane-2,4-dionato)copper(II) and some heterocycles. Part 2. The 1 : 1 adducts with aza-aromatic compounds and azacyclohexanes
Tamizo Kogane Reiko Hirota Kazuhisa Abe and Minoru Hirota
pg 652; DOI:
10.1039/P29810000652
PDF
Free energy relationships of ionization energies measured by ultraviolet photoelectron spectroscopy in substituted pyrroles
Carla Cauletti Carlo Giancaspro Anna Monaci and M. Novella Piancastelli
pg 656; DOI:
10.1039/P29810000656
PDF
Stereochemistry of a novel sesquiterpene lactone. X-Ray determination of the structure of ursiniolide a monohydrate
Urszula Rychlewska
pg 660; DOI:
10.1039/P29810000660
PDF
The pyridine-catalysed reaction of methanol with phenyl isocyanate in tetrachloromethane
Roy B. Moodie and Peter J. Sansom
pg 664; DOI:
10.1039/P29810000664
PDF
The one-electron reduction of carbonium ions. Part 14. Effect of successive introduction of methyl substituents on the reducibility of tropylium ion in chromium(II) ion and cathodic reductions
Ken'ichi Takeuchi Takeshi Kurosaki Yasunori Yokomichi Yoshihiro Kimura Yasuhiro Kubota Hiroshi Fujimoto and Kunio Okamoto
pg 670; DOI:
10.1039/P29810000670
PDF
Electrophilic aromatic substitution. Part 28. Rate factors for protiodetritiation of all positions of hexahelicene (benzo[c]naphtho-[1,2g]phenanthrene): the reactivity of bent benzene rings
William J. Archer Yousif El-Din Shafig and Roger Taylor
pg 675; DOI:
10.1039/P29810000675
PDF
Kinetic hydrogen isotope effects in intermolecular hydride transfer from arylalkanes to 9-arylfluoren-9-yl cations
Donald Bethell Gerard J. Hare and Paul A. Kearney
pg 684; DOI:
10.1039/P29810000684
PDF
Photolysis of the carbon–hydrogen bond in pentamethylcyclopentadiene. Properties of the pentamethylcyclopentadienyl radical
Alwyn G. Davies and Janusz Lusztyk
pg 692; DOI:
10.1039/P29810000692
PDF
Optical rotatory dispersion and absolute configuration. Part 32. Circular dichroism and conformation of 3-hydroxypiperidines
Bjorn Ringdahl Ulrich F. W. Ohnsorge and J. Cymerman Craig
pg 697; DOI:
10.1039/P29810000697
PDF
The relative efficiencies of a number of nitrite traps at different acidities and bromide ion concentrations
Gwenda Ellison and D. Lyn H. Williams
pg 699; DOI:
10.1039/P29810000699
PDF
Reactions of the methylthiyl radical with unsaturated cycloalkanes: abstraction, addition, and rearrangement
Lodovico Lunazzi Giuseppe Placucci and Loris Grossi
pg 703; DOI:
10.1039/P29810000703
PDF
The role of solvent in the mechanism of protonation of benzene and ethylene
Tomás Sordo Monserrat Arumi and Juan Bertrán
pg 708; DOI:
10.1039/P29810000708
PDF
Mechanisms for aromatic photocyanation: naphthalene and biphenyl
Nigel J. Bunce John P. Bergsma and John L. Schmidt
pg 713; DOI:
10.1039/P29810000713
PDF
The separation of polar and steric effects. Part 15. Kinetics of the reactions of benzoic acid and of ortho-substituted benzoic acids with diazodiphenylmethane in various aprotic solvents
M. Hanif Aslam Norman B. Chapman John Shorter and Marvin Charton
pg 720; DOI:
10.1039/P29810000720
PDF
The determination, by 1H nuclear magnetic resonance studies, of some stereochemical features in the alkaloids isocorymine, erinine, erinicine, and eripine
Frank Heatley David I. Bishop and John A. Joule
pg 725; DOI:
10.1039/P29810000725
PDF
Conformational analysis of tryptophan in solution using nuclear magnetic resonance methods
Bruce Dezube Christopher M. Dobson and Catherine E. Teague
pg 730; DOI:
10.1039/P29810000730
PDF
The type a zwitterion in cyclohexadienone photochemistry: chemical trapping and stereochemistry
Christopher J. Samuel
pg 736; DOI:
10.1039/P29810000736
PDF
Determination of ring inversion barriers for 1H,3H-naphtho[1,8-cd]-pyran and its methyl substituted derivatives by molecular mechanics calculations and dynamic nuclear magnetic resonance spectroscopy
J. Edgar Anderson and Flemming S. Jørgensen
pg 741; DOI:
10.1039/P29810000741
PDF
The electron spin resonance spectrum of the fulvalene radical anion
Alwyn G. Davies Jeremy R. M. Giles and Janusz Lusztyk
pg 747; DOI:
10.1039/P29810000747
PDF

Issue 5


Front cover

pg X017; DOI:
10.1039/P298100FX017
PDF
Contents pages

pg P017; DOI:
10.1039/P298100FP017
PDF
Back cover

pg X019; DOI:
10.1039/P298100BX019
PDF
Carbon-13 substituent chemical shifts in the side-chain carbons of aromatic systems: the importance of -polarization in determining chemical shifts
John Bromilow Robert T. C. Brownlee David J. Craik Peter R. Fiske Jeffrey E. Rowe and Maruse Sadek
pg 753; DOI:
10.1039/P29810000753
PDF
A theoretical investigation of the -polarization mechanism. The importance of localized and extended polarization
Robert T. C. Brownlee and David J. Craik
pg 760; DOI:
10.1039/P29810000760
PDF
Molecular interactions in non-aqueous solvents. Part 3. Kinetics and energetics of dimerization of a tetrasubstituted copper(II) phthalocyanine dye
Richard C. Graham Edward M. Eyring and Gary H. Henderson
pg 765; DOI:
10.1039/P29810000765
PDF
Metastable decomposition of C3H6O+ ions
David J. McAdoo and Dennis N. Witiak
pg 770; DOI:
10.1039/P29810000770
PDF
The wavelength- and solvent-dependent photochemistry of 1,1-dicyano-2-methyl-4-phenylbut-1-ene; reaction from two excited states1
Richard C. Cookson David E. Sadler and Kingsley Salisbury
pg 774; DOI:
10.1039/P29810000774
PDF
Proton and carbon-13 nuclear magnetic resonance studies of substituted pyrimidines. Part 6. Carbon-13-proton coupling constants for some monoprotonated methyl- and amino-pyrimidines
Jacques Riand Claude Coupry and Marie-Thérèse Chenon
pg 783; DOI:
10.1039/P29810000783
PDF
The structures of the products of three condensation reactions. Crystal and molecular structures of 5,6-dihydrothiazolo[2,3-c][1,2,4]-thiadiazol-3-one, 6-(1-ethyl-1-hydroxypropyl)-5-phenyl-2,3,5,6-tetrahydro-imidazo[2,1-b]thiazole, and 5,5-diphenyl-2,3-dihydroimidazo-[2,1-b]thiazol-6(5H)-one
A. Forbes Cameron Ian R. Cameron and Fergus D. Duncanson
pg 789; DOI:
10.1039/P29810000789
PDF
Photogalvanic cells. Part 14. The synthesis and characterization of disulphonated thionines
W. John Albery Philip N. Bartlett Andrew W. Foulds Fernando A. Souto-Bachiller and Robert Whiteside
pg 794; DOI:
10.1039/P29810000794
PDF
The electrochemical reduction of NN-disubstituted 6-phenyl-2,3-dihydro-1,4-diazepinium salts: formation of bis(tetrahydrodiazepinyls) and a di-imidazolidinylbutadiene
Douglas Lloyd Colin A. Vincent and David J. Walton
pg 801; DOI:
10.1039/P29810000801
PDF
The stabilities of Meisenheimer complexes. Part 26. The reactions of some aromatic nitro-compounds with base in t-butyl alcohol–water mixtures
Ahmad D. A. AlAruri and Michael R. Crampton
pg 807; DOI:
10.1039/P29810000807
PDF
Nuclear magnetic resonance study of the protonation of 2,6-dimethyl--pyrone and related bases in superacid systems
Victor Gold and Talat Mah
pg 812; DOI:
10.1039/P29810000812
PDF
Oxidation by cobalt(III) acetate. Part 3. Allylic oxidation of various olefins in acetic acid
Masao Hirano Kouji Nakamura and Takashi Morimoto
pg 817; DOI:
10.1039/P29810000817
PDF
Anion activation by the bulky perhydrotribenzo[2.2.2]cryptand in aqueous–organic two-phase systems and in low polarity media. A comparison with the anionic reactivity induced by [2.2.2,C14]cryptand
Dario Landini Angelamaria Maia Fernando Montanari and Franco Rolla
pg 821; DOI:
10.1039/P29810000821
PDF
The anodic oxidation of 1,4-diaminobenzene: an electron spin resonance and electrochemical study
W. John Albery Richard G. Compton and Ian S. Kerr
pg 825; DOI:
10.1039/P29810000825
PDF
Acetyl exchange between acetyl chloride and sterically hindered aryl ketones under Friedel–Crafts conditions
Andreas D. Andreou Roger V. Bulbulian Peter H. Gore Donald F. C. Morris and Eric L. Short
pg 830; DOI:
10.1039/P29810000830
PDF
The reaction of CH4+, CH3+, and other simple carbocations with benzene in the gas phase
James D. Morrison Keith Stanney and John M. Tedder
pg 838; DOI:
10.1039/P29810000838
PDF
Electrophilic aromatic substitution. Part 25. The nitration in aqueous sulphuric acid of some cinnamic acids and other styrene derivatives
Roy B. Moodie Kenneth Schofield Peter G. Taylor and Philip J. Baillie
pg 842; DOI:
10.1039/P29810000842
PDF
Electrophilic aromatic substitution. Part 26. The kinetics and mechanism of nitration of some reactive benzene derivatives in aqueous phosphoric acid. The identification of steps rate-limited by nitronium ion formation and by diffusion
Hugh W. Gibbs Lyndsay Main Roy B. Moodie and Kenneth Schofield
pg 848; DOI:
10.1039/P29810000848
PDF
Free radical studies by resonance Raman spectroscopy: phenothiazine, 10-methylphenothiazine, and phenoxazine radical cations
Ronald E. Hester and Kenneth P. J. Williams
pg 852; DOI:
10.1039/P29810000852
PDF
Configurations and conformations of the oximes, O-methyl oximes, and N-methylnitrones derived from chalcones
Denis W. Clack Nadir Khan and David A. Wilson
pg 860; DOI:
10.1039/P29810000860
PDF
An electron spin resonance study of radical addition to bis(trimethylsilyl)amino(trimethylsilylimino)phosphine, (Me3Si)2NPNSiMe3
Brian P. Roberts and Karamjit Singh
pg 866; DOI:
10.1039/P29810000866
PDF
The crystal and molecular structure of (S)-(+)- and racemic 9,10-dihydrodibenzo[c,g]phenanthrene
Reiko Kuroda and Stephen F. Mason
pg 870; DOI:
10.1039/P29810000870
PDF

Issue 6


Front cover

pg X021; DOI:
10.1039/P298100FX021
PDF
Contents pages

pg P021; DOI:
10.1039/P298100FP021
PDF
Back cover

pg X023; DOI:
10.1039/P298100BX023
PDF
The crystal structures of a ketone and related acetal macrocycle containing 2,6-pyridino and polyether subunits
Frank R. Fronczek Steven F. Watkins and George R. Newkome
pg 877; DOI:
10.1039/P29810000877
PDF
The kinetics of the reactions of picryl chloride with some substituted anilines. Part 7. 2-Substituted and 2,5-disubstituted anilines
Thomas A. Emokpae Jonathan M. Nwaedozie and Jack Hirst
pg 883; DOI:
10.1039/P29810000883
PDF
Benzoquinone imines. Part 17. Kinetics and mechanism of the hydrolysis and cyclization of 2-aminoindophenols in aqueous solution
Keith C. Brown and John F. Corbett
pg 886; DOI:
10.1039/P29810000886
PDF
Free radical reactions of the phenothiazine, metiazinic acid
Detlef Bahnemann Klaus-Dieter Asmus and Robin L. Willson
pg 890; DOI:
10.1039/P29810000890
PDF
Verdazyls. Part 30. N-1,N-1-linked biverdazyls (bis-1,2,3,4-tetrahydro-s-tetrazin-1-yls) with a [2.2]paracyclophanylene bridge
Franz A. Neugebauer and Hans Fischer
pg 896; DOI:
10.1039/P29810000896
PDF
The kinetics and mechanism of the spontaneous hydrolysis of 4-chlorophenyl isocyanate in diethyl ether solution
Rosemary S. Satchell and Roger Nyman
pg 901; DOI:
10.1039/P29810000901
PDF
A laser flash photolysis study of t-butoxyphosphoranyl radicals. Optical spectra and kinetics of formation, fragmentation, and rearrangement
Brian P. Roberts and Juan C. Scaiano
pg 905; DOI:
10.1039/P29810000905
PDF
Nuclear magnetic resonance investigations of iminium ion intermediates. Part 9. Multinuclear study of the reaction between Lewis acids and vinylogous amides
Jean Dorie Jean-Paul Gouesnard and Maryvonne L. Martin
pg 912; DOI:
10.1039/P29810000912
PDF
The fluorescence of some dipolar NN-dialkyl-4-(dichloro-1,3,5-triazinyl)anilines. Part 2. Temperature and solvent effects on the radiationless decay of an intramolecular charge-transfer excited singlet state
David J. Cowley and Ishrat Pasha
pg 918; DOI:
10.1039/P29810000918
PDF
Spontaneous and base-catalysed elimination from 1-ferrocenylalkyl cations
Clifford A. Bunton Nelson Carrasco Faegh Davoudzadeh and William E. Watts
pg 924; DOI:
10.1039/P29810000924
PDF
Protiodesilylation of substituted 2-trimethylsilylthiophens
Giancarlo Seconi and Colin Eaborn
pg 931; DOI:
10.1039/P29810000931
PDF
Dienone–phenol rearrangements of bicyclic cyclohexa-2,5-dien-1-ones; kinetic studies of the importance of a multistage mechanism
Anthony J. Waring Javid Hussain Zaidi and James W. Pilkington
pg 935; DOI:
10.1039/P29810000935
PDF
Solvolysis of some alkyl esters of fluorosulphuric acid in water and aqueous solvents
Lázaro F. R. Cafferata Osvaldo E. Desvard and Juan E. Sicre
pg 940; DOI:
10.1039/P29810000940
PDF
The hydrogen-stretching absorptions and conformations of tetralin-1-ol, chroman-4-ol, thiochroman-4-ol, and indan-1-ol derivatives
Kaoru Hanaya Shinji Onodera Yusaku Ikegami Hideaki Kudo and Keisuke Shimaya
pg 944; DOI:
10.1039/P29810000944
PDF
Cyclopropane ring opening of bicyclo[3.1.0]hexan-3-ols in fluorosulphuric acid
John C. Rees and David Whittaker
pg 948; DOI:
10.1039/P29810000948
PDF
Opening of the cyclopropane ring of the thujan-3-ols in fluorosulphuric acid
John C. Rees and David Whittaker
pg 953; DOI:
10.1039/P29810000953
PDF
Unimolecular reactions of isolated organic ions: some isomers of C6H14+
Jens F. Wendelboe Richard D. Bowen and Dudley H. Williams
pg 958; DOI:
10.1039/P29810000958
PDF
The reactions of some common electrophiles, CH3+, NO+, NO2+, and O2NCH2+, with monosubstituted benzenes in the gas phase
James D. Morrison Keith Stanney and John M. Tedder
pg 967; DOI:
10.1039/P29810000967
PDF
The ring-opening reactions of cyclobutylmethyl and cyclobutenylmethyl radicals
Keith U. Ingold Bernard Maillard and John C. Walton
pg 970; DOI:
10.1039/P29810000970
PDF
Perfluoro effects in 15N nuclear magnetic resonance spectroscopy. Part 1. Aryl and N-heteroaryl azides
D. Magan Kanjia Joan Mason Ian A. Stenhouse Ronald E. Banks and Narinder D. Venayak
pg 975; DOI:
10.1039/P29810000975
PDF
X-Ray crystallographic determination of the molecular structures of cis- and trans-isomers of ()-5-fluorocyclophosphamide {2-[bis-(2-chloroethyl)amino]-5-fluorotetrahydro-2H-1,3,2-oxazaphosphorine 2-oxide]}
Shirley D. Cutbush Stephen Neidle Graham N. Taylor and John L. Gaston
pg 980; DOI:
10.1039/P29810000980
PDF

Issue 7


Front cover

pg X025; DOI:
10.1039/P298100FX025
PDF
Contents pages

pg P025; DOI:
10.1039/P298100FP025
PDF
Back cover

pg X027; DOI:
10.1039/P298100BX027
PDF
-, -, and -Deuterium isotope effects in the solvolysis of octan-2-yl p-bromobenzenesulphonate in 88% aqueous trifluoroethanol and 83% aqueous hexafluoroisopropyl alcohol
George A. Gregoriou and Fannie S. Varveri
pg 985; DOI:
10.1039/P29810000985
PDF
Photoelectron spectroscopic studies of some 2-azabicyclo[2.2.2]octan-5-one and bicyclo[2.2.2]octanone derivatives
Frank Carnovale Tiang-Hong Gan J. Barrie Peel and Andrew B. Holmes
pg 991; DOI:
10.1039/P29810000991
PDF
Reactions of nitroanisoles. Part 2. Reactions of 2,4- and 2,6-dinitroanisole with piperidines in benzene
N. Sbarbati Nudelman and Daniel Palleros
pg 995; DOI:
10.1039/P29810000995
PDF
Synthesis, stereochemistry, and molecular and crystal structure of exo-3-phenyl-3-phosphabicyclo[3.2.1]oct-6-ene 3-oxide

pg 1000; DOI:
10.1039/P29810001000
PDF
Preparation and spectroscopic properties of pure tetrabenzoporphyrins
Rob B. M. Koehorst Joop F. Kleibeuker Tjeerd J. Schaafsma Dick A. de Bie Bart Geurtsen Robert N. Henrie and Henk C. van der Plas
pg 1005; DOI:
10.1039/P29810001005
PDF
Photocyclization of aryl halides. Part 2. The upper excited state reactivity of 3-(2-halogenoanilino)-1,3-diphenylprop-2-enones; hydrogen-bonded configurational lock in photosynthesis
James Grimshaw and A. Prasanna de Silva
pg 1010; DOI:
10.1039/P29810001010
PDF
Naphthalene tetrachlorides and related compounds. Part 10. The carbon-13 nuclear magnetic resonance spectra of some naphthalene tetrachlorides
Graham A. Bowmaker David Calvert Peter B. D. de la Mare and Bernice C. J. McKellar
pg 1015; DOI:
10.1039/P29810001015
PDF
Alkyl nitrites as nitrosating agents. Kinetics and mechanism of the reactions of propyl nitrite in propan-1-ol
S. Elaine Aldred and D. Lyn H. Williams
pg 1021; DOI:
10.1039/P29810001021
PDF
Complex formation between guanidinium nitrate and 1,4,7,10,13,16-hexaoxacyclo-octadecane (18-crown-6). Crystal structure of the hydrogen-bonded 2 : 1 complex
Judith A. Bandy (née Herbert) Mary R. Truter Jonathan N. Wingfield and John D. Lamb
pg 1025; DOI:
10.1039/P29810001025
PDF
High-resolution 13C nuclear magnetic resonance spectra of some solid trans-azobenzene and dyestuff species
A. Margaret Chippendale Alan Mathias Robin K. Harris Kenneth J. Packer and Barry J. Say
pg 1031; DOI:
10.1039/P29810001031
PDF
Reactions of oxygenated radicals in the gas phase. Part 8. Reactions of alkoxyl radicals with aldehydes and ketones
Nageh Y. Al Akeel Keith Selby and David J. Waddington
pg 1036; DOI:
10.1039/P29810001036
PDF
Methanolysis of the benzylideneaniline derivatives ArC(MMe3)NAr' (M = Si or Sn)
Giancarlo Seconi Graziella Pirazzini Alfredo Ricci Mariella Fiorenza and Colin Eaborn
pg 1043; DOI:
10.1039/P29810001043
PDF
Cleavages of 1-methyl-2-trimethylsilylbenzimidazole and 2-trimethylsilylbenzothiazole in methanol and related media
Giancarlo Seconi and Colin Eaborn
pg 1051; DOI:
10.1039/P29810001051
PDF
Complexation between 3-methylorotic (3-methyluracil-6-carboxylic) acid dianion and divalent metal cations. The slow acid dissociation of transition metal complexes and its possible relevance to orotic acid phosphoribosylation
Denis Lalart Jean Guillerez Guy Dodin and Jacques-Emile Dubois
pg 1057; DOI:
10.1039/P29810001057
PDF
The stability of the carbenes from 1,2-dithiole and 1,3-dithiole in relation to the synthesis of 1,1,3,3- and 1,1,2,2-tetrathiafulvalenes
Carl Th. Pedersen Jens Oddershede and John R. Sabin
pg 1062; DOI:
10.1039/P29810001062
PDF
Electron spin resonance studies. Part 60. Detection of radicalcations from vinyl sulphides: evidence for a cyclic structure
Bruce C. Gilbert Richard O. C. Norman and Peter S. Williams
pg 1066; DOI:
10.1039/P29810001066
PDF
The Mc activity coefficient function for acid–base equilibria. Part 5. The Mc activity coefficient for a reliable estimate of thermodynamic values
Nunziata C. Marziano Alberto Tomasin and Pietro G. Traverso
pg 1070; DOI:
10.1039/P29810001070
PDF
Small rings. Part 32. The gas phase kinetics, mechanism, and energy hypersurface for the thermolyses of syn- and anti-tricyclo[4.2.0.0]-octane
Robin Walsh Hans-Dieter Martin Michael Kunze Alfred Oftring and Hans-Dieter Beckhaus
pg 1076; DOI:
10.1039/P29810001076
PDF
A hyperbolic modification of linear free energy relationships
Edward S. Lewis Celia C. Shen and Rory A. More O'Ferrall
pg 1084; DOI:
10.1039/P29810001084
PDF
Tautomerism in a thioamide-nitroxide: solvent effects in terms of an electron spin resonance parameter for a 2-thiocarbonylimidazolidine 1-oxyl
Raphael Darcy
pg 1089; DOI:
10.1039/P29810001089
PDF
Electrogeneration of cyanomethyl anion from phenylsulphonylacetonitrile and cyanomethyltrimesitylphosphonium iodide and the relative acidities of XCH2CN (X = Ph3P+, Ph3As+, Mes3P+, or PhSO2)versus acetic acid in acetonitrile
Anthony J. Bellamy and Iain S. Mackirdy
pg 1093; DOI:
10.1039/P29810001093
PDF
Restricted rotation in methyl- and cyanomethyl-tris-(2,4,6-trimethylphenyl)phosphonium compounds. A 1H nuclear magnetic resonance spectroscopic study. The crystal structure of cyanomethyltris-(2,4,6-trimethylphenyl)phosphonium tetraiodomercurate(II)
Anthony J. Bellamy Robert O. Gould and Malcolm D. Walkinshaw
pg 1099; DOI:
10.1039/P29810001099
PDF
Kinetics of the reactions of phenyl 2,4,6-trinitrophenyl ether with piperidine, n-butylamine, aniline, benzylamine, and morpholine in benzene

pg 1105; DOI:
10.1039/P29810001105
PDF

Issue 8


Front cover

pg X029; DOI:
10.1039/P298100FX029
PDF
Contents pages

pg P029; DOI:
10.1039/P298100FP029
PDF
Back cover

pg X031; DOI:
10.1039/P298100BX031
PDF
Aroyl peroxides. Part 7. The effects of additives on the thermolysis of aroyl peroxides in arenes and the elimination of possible complications in the measurement of partial rate factors for phenylation
Roger Bolton Bryce N. Dailly Kazuko Hirakubo Kong Hung Lee and Gareth H. Williams
pg 1109; DOI:
10.1039/P29810001109
PDF
Free radical reactions in solution. Part 6. Thermal decomposition of substituted dibenzyl mercurials in solution. An improved scale
Suphi Dinçtürk Richard A. Jackson Michael Townson Hikmet Airba Norman C. Billingham and Gary March
pg 1121; DOI:
10.1039/P29810001121
PDF
Free radical reactions in solution. Part 7. Substituent effects on free radical reactions: comparison of the scale with other measures of radical stabilization
Suphi Dinçtürk and Richard A. Jackson
pg 1127; DOI:
10.1039/P29810001127
PDF
An electron spin resonance study of 3-oxypropenoyl radicals derived from glycidols
Alwyn G. Davies Jalal A.-A. Hawari Brenda Muggleton and Man-Wing Tse
pg 1132; DOI:
10.1039/P29810001132
PDF
Synthesis, stereochemistry, and crystal and molecular structure of 4-bromo-1,2,2,3-tetramethyl-1-phenylphosphetanium bromide

pg 1138; DOI:
10.1039/P29810001138
PDF
Electron spin resonance study of inversion and conformations in 1-hydroxycyclohexyl radicals
Roger V. Lloyd and J. Guy Causey
pg 1143; DOI:
10.1039/P29810001143
PDF
An electron spin resonance investigation of the radical anions of the benzoylpyridines
Arjen J. L. Sevenster and Brian J. Tabner
pg 1148; DOI:
10.1039/P29810001148
PDF
Electrophilic aromatic substitution. Part 29. Protiodetritiation of 4H-cyclopenta[def]phenanthrene: the substituent activation factor Af
William J. Archer and Roger Taylor
pg 1153; DOI:
10.1039/P29810001153
PDF
The dependence on temperature of rate constants for solvolysis of alkyl halides and related compounds in water
Michael J. Blandamer John Burgess Phillip P. Duce Ross E. Robertson and John W. M. Scott
pg 1157; DOI:
10.1039/P29810001157
PDF
13C and 1H nuclear magnetic resonance study of solvent effects on tautomerism in 1-aryl-3-methyltriazenes
Donald L. Hooper and Keith Vaughan
pg 1161; DOI:
10.1039/P29810001161
PDF
Gas phase thermolyses. Part 4. Gas phase thermolyses of thietan 1-oxide and 1,2-oxathiolan 2-oxide. Evidence for the intermediacy of 1,2-oxathiolan
Lars Carlsen Helge Egsgaard and David N. Harpp
pg 1166; DOI:
10.1039/P29810001166
PDF
Ultraviolet spectra of dehydropeptides by double beam measurement
Yasuyuki Shimohigashi James W. Dunning jun. Michael D. Grim and Charles H. Stammer
pg 1171; DOI:
10.1039/P29810001171
PDF
Kinetics and mechanism of the oxidation of 3,5-di-t-butyl-o-benzoquinone with hydrogen peroxide in aqueous methanol solution
Gábor Speier and Zoltán Tyeklár
pg 1176; DOI:
10.1039/P29810001176
PDF
Unstable intermediates. Part 194. Alkyl radical–halide ion adducts: an electron spin resonance study of the radiolysis of a range of alkyl bromides and iodides
Martyn C. R. Symons and Ian G. Smith
pg 1180; DOI:
10.1039/P29810001180
PDF
Radical reactions of carbohydrates. Part 2. An electron spin resonance study of the oxidation of D-glucose and related compounds with the hydroxyl radical
Bruce C. Gilbert David M. King and C. Barry Thomas
pg 1186; DOI:
10.1039/P29810001186
PDF

Issue 9


Front cover

pg X033; DOI:
10.1039/P298100FX033
PDF
Front matter

pg P033; DOI:
10.1039/P298100FP033
PDF
Back cover

pg X035; DOI:
10.1039/P298100BX035
PDF
Kinetics of the reactions of aniline and 2,2,2-trifluoroethylamine with 1,3,5-trinitrobenzene in dimethyl sulphoxide and acetonitrile, and of 2,2,2-trifluoroethylamine with 1-fluoro- and 1-chloro-2,4-dinitrobenzenes in these solvents
Titus O. Bamkole Jack Hirst and Ikenna Onyido
pg 1201; DOI:
10.1039/P29810001201
PDF
Substituent effects in infrared spectroscopy. Part 6. meta- and para-Substituted N-ammoniobenzamidates
Christian Laurence Michel Berthelot Maryvonne Luçon David G. Morris and Alistair G. Shepherd
pg 1206; DOI:
10.1039/P29810001206
PDF
Electron spin resonance studies of thiophosphoranyl radicals. The mechanism of ligand permutation in phosphoranyl radicals
Jeremy R. M. Giles and Brian P. Roberts
pg 1211; DOI:
10.1039/P29810001211
PDF
Kinetics and intermediates in the several forward and reverse reactions of nitro-substituted arenediazonium ions with hydroxide ion
Paul D. Goodman Terence J. Kemp and Peter Pinot de Moira
pg 1221; DOI:
10.1039/P29810001221
PDF
Radical-induced hydrogen exchange in the presence of reducing transition metal ions
Victor Gold Susan M. Pemberton and David L. Wood
pg 1230; DOI:
10.1039/P29810001230
PDF
Flash photolysis study of phenyl-substituted phenols, quinones, and corresponding free radicals. Part 2. Dimerisation of 2,6-diphenyl-4-methoxyphenoxyl radical in various solvents
Igor V. Khudyakov Petr. P. Levin jun. Vladimir A. Kuz'min Hendrik J. Hageman and Cornelis R. H. I. de Jonge
pg 1234; DOI:
10.1039/P29810001234
PDF
Flash photolysis study of phenyl-substituted phenols, quinones, and corresponding free radicals. Part 3. Intermediates in the photolysis of phenyl-substituted phenols
Petr. P. Levin jun. Igor V. Khudyakov Vladimir A. Kuz'min Hendrik J. Hageman and Cornelis R. H. I. de Jonge
pg 1237; DOI:
10.1039/P29810001237
PDF
Unsymmetrically substituted furoxans. Part 6. 3-Nitro-4-phenylfuroxan: reaction with sodium methoxide and X-ray structural analysis
Rosella Calvino Alberto Gasco Anna Serafino and Davide Viterbo
pg 1240; DOI:
10.1039/P29810001240
PDF
Kinetics and mechanism of the reaction of substituted phenylhydrazones with thallium(III) acetate. Reactions of mercury(II) acetate with nitrogen compounds. Part 8
Richard N. Butler Gerard J. Morris and Anne M. O'Donohue
pg 1243; DOI:
10.1039/P29810001243
PDF
A kinetic analysis of the acidic degradation of penicillin G and confirmation of penicillamine as a degradation product
David P. Kessler Isaac Ghebre-Sellassie Adelbert M. Knevel and Stanley L. Hem
pg 1247; DOI:
10.1039/P29810001247
PDF
Association of crown ethers with anilinium ions in methanol solution and its influence on acid–base equilibria
Bernardo Masci
pg 1252; DOI:
10.1039/P29810001252
PDF
Gas-phase thermolyses. Part 5. Thermally-induced rearrangement of methyl acetate in the gas phase
Lars Carlsen Helge Egsgaard and Palle Pagsberg
pg 1256; DOI:
10.1039/P29810001256
PDF
The electronic structure of the s-indacenyl dianion. Structural assessment by nuclear magnetic resonance spectroscopy and molecular orbital calculations
Ulf Edlund Bertil Eliasson Jozef Kowalewski and Lars Trogen
pg 1260; DOI:
10.1039/P29810001260
PDF
Conformational equilibria in 1,2-diarylethylenes manifested in their emission in solution. Part 5. 2,6-Distyrylnaphthalene and related compounds
Gabriella Fischer and Ernst Fischer
pg 1264; DOI:
10.1039/P29810001264
PDF
Linear free energy relationships. Part 10. Synthesis, thermal, spectral, electrochemical, and hole transport (conduction) properties of some novel carbazole derivatives
Harry W. Gibson George R. Olin and John M. Pochan
pg 1267; DOI:
10.1039/P29810001267
PDF
Paramagnetic intermediates in the thermal reactions of benzo[2,1-b;3,4-b]dithiophen-4,5-dione with some metal(III) compounds of the heavier group VB elements
Angelo Alberti Andrew Hudson Antonio Maccioni Gianni Podda and Gian Franco Pedulli
pg 1274; DOI:
10.1039/P29810001274
PDF
Induction of instantaneous chain reactions in the peroxodiphosphate–iron(II) system by selected substrates during a titrimetric procedure
Pichai Maruthamuthu and Narayanasamy Subramanian
pg 1280; DOI:
10.1039/P29810001280
PDF
An analysis of the 1H and 13C nuclear magnetic resonance spectra of 3-t-butylaminoacrolein and of glyoxal t-butylhydrazone
Hamish McNab
pg 1283; DOI:
10.1039/P29810001283
PDF
The effect of charge and of electron density on the nuclear magnetic resonance parameters of conjugated systems: some isoelectronic anions and cations
Hamish McNab
pg 1287; DOI:
10.1039/P29810001287
PDF
Dipole moments of derivatives of 4-phenylazo-NN-diethylaniline and of 9-phenylazojulolidine (9-phenylazo-2,3,6,7-tetrahydro-1H,5H-benzo[ij]quinolizine)
Geoffrey Hallas Naghi Saadatjou John D. Hepworth Douglas A. Ibbitson Alan M. Jones Terence P. Keane and Andrew R. Turton
pg 1292; DOI:
10.1039/P29810001292
PDF
Radical-anion intermediates. Part 8. The influence of a crown ether on the fluorene and 9-methylfluorene radical-anions
Brian J. Tabner and Timothy Walker
pg 1295; DOI:
10.1039/P29810001295
PDF
The radical anion of [24](1,2,4,5)cyclophane
Fabian Gerson Javier Lopez and Virgil Boekelheide
pg 1298; DOI:
10.1039/P29810001298
PDF
Kinetic and equilibrium solvent isotope effects on the deprotonation of a salicylate ion by hydroxide ion and general bases
Frank Hibbert
pg 1304; DOI:
10.1039/P29810001304
PDF
Unimolecular solvolysis of some organosilicon perchlorates and iodides
Colin Eaborn and Foad M. S. Mahmoud
pg 1309; DOI:
10.1039/P29810001309
PDF
Model calculations of isotope effects. Part 5. Secondary hydrogen isotope effects in the solvolysis of isopropyl halides
Duncan J. McLennan
pg 1316; DOI:
10.1039/P29810001316
PDF

Issue 10


Front cover

pg X037; DOI:
10.1039/P298100FX037
PDF
Contents pages

pg P037; DOI:
10.1039/P298100FP037
PDF
Back cover

pg X039; DOI:
10.1039/P298100BX039
PDF
Mononuclear heterocyclic rearrangements. Part 7. Evidence for general base catalysis in the rearrangement of the Z-phenylhydrazone of 3-benzoyl-5-phenyl-1,2,4-oxadiazole into 2,5-diphenyl-4-benzoylamino-1,2,3-triazole in dioxan–water
Vincenzo Frenna Nicolò Vivona Giovanni Consiglio Antonino Corrao and Domenico Spinelli
pg 1325; DOI:
10.1039/P29810001325
PDF
A non-destructive reactivity index of carbohydrates: the hydroxy protonation rates in dimethyl sulphoxide
Brigitte Gillet Daniel J. Nicole and Jean-J. Delpuech
pg 1329; DOI:
10.1039/P29810001329
PDF
The steric course of the reaction of ethylene oxide with hydrogen halides in the gas phase
Giuseppe Bellucci Giancarlo Berti Roberto Bianchini Giovanni Ingrosso and Antonio Moroni
pg 1336; DOI:
10.1039/P29810001336
PDF
Ionization constants of 3-substituted propiolic acids in water
Christian Laurence Jean Guillemé and Bernard Kirschleger
pg 1341; DOI:
10.1039/P29810001341
PDF
Conformations and barriers to inversion of seven-membered cyclic oxamides and their monothio- and dithio-analogues: a study by dynamic nuclear magnetic resonance spectroscopy and molecular mechanics
Roland Isaksson and Tommy Liljefors
pg 1344; DOI:
10.1039/P29810001344
PDF
Intramolecular catalysis in the enolisation of -piperidinopropiophenone and its methiodide derivative
Brian G. Cox Paolo De Maria Adamo Fini and Abdi Farah Hassan
pg 1351; DOI:
10.1039/P29810001351
PDF
Electrophilic aromatic substitution. Part 27. Chemical selectivities disguised by mass diffusion. Part 6. The kinetics of nitration in aqueous sulphuric acid of durene (1,2,4,5-tetramethylbenzene), nitrodurene, and nitroprehnitene (nitro-1,2,3,4-tetramethylbenzene). A comparison of the rates of nitration of methylnitrobenzenes in aqueous sulphuric acid with the corresponding rates from mixing–disguised nitrations with nitronium hexafluorophosphate in nitromethane based on a theoretical mixing–reaction model
Ajay K. Manglik Roy B. Moodie Kenneth Schofield Erol Dedeoglu Andreas Dutly and Paul Rys
pg 1358; DOI:
10.1039/P29810001358
PDF
Routes to 3-bromoflavanone from erythro-2-hydroxychalcone dibromide: spectral and kinetic evidence for the dominating role of elimination–addition sequences via(E)- and (Z)--bromo-2-hydroxychalcones
Shantha K. David Lyndsay Main and K. Barry Old
pg 1367; DOI:
10.1039/P29810001367
PDF
Nuclear magnetic resonance studies of the conformation of bilirubin and its derivatives in solution
Doron Kaplan and Gil Navon
pg 1374; DOI:
10.1039/P29810001374
PDF
Linewidth alternation in the electron spin resonance spectrum of the fluorene radical anion in the presence of dibenzo crown ethers
E. John Rothwell and Brian J. Tabner
pg 1384; DOI:
10.1039/P29810001384
PDF
Electron spin resonance studies. Part 61. The generation and reactions of the t-butoxyl radical in aqueous solution
Bruce C. Gilbert P. David R. Marshall Richard O. C. Norman Nelson Pineda and Peter S. Williams
pg 1392; DOI:
10.1039/P29810001392
PDF
Electron spin resonance studies. Part 62. Acid-catalysed interconversion of -hydroxyalkyl radicals: radical-cation intermediates
Bruce C. Gilbert Richard O. C. Norman and Peter S. Williams
pg 1401; DOI:
10.1039/P29810001401
PDF
The kinetics and mechanism of the hydrolysis of thiol esters in aqueous solution promoted by tetrachlorogold(III) ions
Geeta Patel Rosemary S. Satchell and Derek P. N. Satchell
pg 1406; DOI:
10.1039/P29810001406
PDF
Conformation and stereodynamics of 2-dialkylamino-1,3-dimethyl-2,3-dihydro-1H-1,3,2-benzodiazaphospholes. An experimental nuclear magnetic resonance, ultraviolet photoelectron, and theoretical MNDO investigation
W. Brian Jennings David Randall S. Davis Worley and J. Howard Hargis
pg 1411; DOI:
10.1039/P29810001411
PDF

Issue 11


Front cover

pg X041; DOI:
10.1039/P298100FX041
PDF
Contents pages

pg P041; DOI:
10.1039/P298100FP041
PDF
Back cover

pg X043; DOI:
10.1039/P298100BX043
PDF
The photochemistry of sulphoxides. A CIDNP study of carbon–sulphur bond cleavage paths
Igor Khait Reinhard Lüdersdorf Karol A. Muszkat and Klaus Praefcke
pg 1417; DOI:
10.1039/P29810001417
PDF
Gas-phase methylation of phenol and anisole by CH3XCH3+(X = F, Cl, or Br) ions
Nicola Pepe and Maurizio Speranza
pg 1430; DOI:
10.1039/P29810001430
PDF
Thermal decomposition of diazodiphenylmethane catalysed by sulphur compounds in the presence of oxygen
Luisa Benati Pier Carlo Montevecchi and Piero Spagnolo
pg 1437; DOI:
10.1039/P29810001437
PDF
pH-Dependent fluorescence spectroscopy. Part 12. Flavone, 7-hydroxyflavone, and 7-methoxyflavone
Rudolf Schipfer Otto S. Wolfbeis and Andreas Knierzinger
pg 1443; DOI:
10.1039/P29810001443
PDF
Conformational studies by dynamic nuclear magnetic resonance spectroscopy. Part 21. Structure, conformation, and stereodynamics of sulphinylhydrazines
Giovanni Cerioni Pierpaolo Piras Giaime Marongiu Dante Macciantelli and Lodovico Lunazzi
pg 1449; DOI:
10.1039/P29810001449
PDF
Phenylhydrazone derivatives of Meldrum's acid: crystal and molecular structures of 2,2-dimethyl-1,3-dioxan-4,5,6-trione 5-(2-nitrophenylhydrazone)(1) and 2,2-dimethyl-1,3-dioxan-4,5,6-trione 5-(2-chlorophenylhydrazone)(2)
Brian Vickery Gerald R. Willey and Michael G. B. Drew
pg 1454; DOI:
10.1039/P29810001454
PDF
An investigation of the two-step nature of the Sandmeyer reaction
Carlo Galli
pg 1459; DOI:
10.1039/P29810001459
PDF
MNDO study of the site of protonation in methylsydnone
Mirjana Eckert-Maksi and Zvonimir B. Maksi
pg 1462; DOI:
10.1039/P29810001462
PDF
Structural studies of some serrulatane diterpenes
Sydney R. Hall Colin L. Raston Brian W. Skelton and Allan H. White
pg 1467; DOI:
10.1039/P29810001467
PDF
Intramolecular [2 + 2] photoaddition of a 1,7-diene
Kevin D. Croft Emilio L. Ghisalberti Phillip R. Jefferies Alan D. Stuart Colin L. Raston and Allan H. White
pg 1473; DOI:
10.1039/P29810001473
PDF
Alteration of the cis: trans isomer ratio in N-methylformamide using lanthanide shift reagents. Determination of the equilibrium constants for complexation
Laurine LaPlanche Graham
pg 1481; DOI:
10.1039/P29810001481
PDF
Kinetic deuterium solvent isotope effects on the general acid-catalysed dissociation of metal cryptates
Brian G. Cox Wojciech Jedral Paul Firman and Hermann Schneider
pg 1486; DOI:
10.1039/P29810001486
PDF
Heterocyclic free radicals. Part 10. Phenothiazine cation-radicals as probes of the inductive effect
Peter Hanson William J. Isham Robin J. Lewis and William A. Stockburn
pg 1492; DOI:
10.1039/P29810001492
PDF
The effect of salt formation on structure and charge distribution in imines. Part 4. Energy barriers to isomerisation about the C–N bond in 2,6-dimethyl-4-aryliminopyrans and their salts: solvent and substituent effects, and evidence for isomerisation mechanisms
Michael P. Sammes
pg 1501; DOI:
10.1039/P29810001501
PDF
The influence of crown ethers on the rate of intramolecular cation exchange involving the 5,12-dihydrotetracene radical anion
Brian J. Tabner and Timothy Walker
pg 1508; DOI:
10.1039/P29810001508
PDF
Organic peroxides. Part 12. The preparation and properties of some triazinyl peroxides
Alwyn G. Davies and Roger Sutcliffe
pg 1512; DOI:
10.1039/P29810001512
PDF
Electro-organic reactions. Part 17. The competition between cleavage and ylid formation in the cathodic reduction of benzyl-, allyl-, cinnamyl-, and polyenyl-phosphonium salts
Vera L. Pardini Loic Roullier James H. P. Utley and Andrew Webber
pg 1520; DOI:
10.1039/P29810001520
PDF

Issue 12


Front cover

pg X045; DOI:
10.1039/P298100FX045
PDF
Contents pages

pg P045; DOI:
10.1039/P298100FP045
PDF
Back cover

pg X047; DOI:
10.1039/P298100BX047
PDF
Crystal and molecular structure of a photoisomer of an oxodipyrromethene: the E-isomer of 3,4-dimethyl-2,2-pyrromethen-5(1H)-one
Akira Hori Stefano Mangani Gerard Pèpe Edgar F. Meyer jun. David L. Cullen Heinz Falk and Karl Grubmayr
pg 1525; DOI:
10.1039/P29810001525
PDF
The circular dichroism of (–)-(S)-3-methylthian: a study of the electronic transitions and stereochemistry of cyclic sulphur derivatives
Giovanni Gottarelli Paolo Mariani Gian Piero Spada Paolo Palmieri and Bruno Samorì
pg 1529; DOI:
10.1039/P29810001529
PDF
Studies on mesoionic compounds. Part 4. Protonation equilibria of 2,3-diaryl-2H-tetrazolium-5-thiolates and 1,3,4-thiadiazolium-2-thiolates in aqueous perchloric acid solutions
A. Mageed Kiwan and Galila A. Wanas
pg 1534; DOI:
10.1039/P29810001534
PDF
Mechanism of base-catalysed hydrogen–deuterium exchange in thiazolium ion: evidence for the involvement of a tetrahedral intermediate
Khashayar Karimian Fatemeh Mohtarami and Massoud Askari
pg 1538; DOI:
10.1039/P29810001538
PDF
Chemical ionisation mass spectra of selected C4H8O compounds
Richard D. Bowen and Alex G. Harrison
pg 1544; DOI:
10.1039/P29810001544
PDF
Crystal and molecular structure of an eight-membered cyclic imidosulphite, 2-(2,4,6-trichlorophenylimino)perhydro-1,3,2,6-dioxathiazocine
Claude Picard Louis Cazaux and Joël Jaud
pg 1554; DOI:
10.1039/P29810001554
PDF
Relationship of the 17O chemical shift to the stretching frequency of the hydroxy-group in saturated alcohols
Mamoru Takasuka
pg 1558; DOI:
10.1039/P29810001558
PDF
Kinetic and equilibrium acid–base properties of strong naphthalene-diamine bases
Frank Hibbert and Kenneth P. P. Hunte
pg 1562; DOI:
10.1039/P29810001562
PDF
1,8-Dimorpholinonaphthalene: proton transfer reactions
Abdul Awwal Richard Burt and A. Jenny Kresge
pg 1566; DOI:
10.1039/P29810001566
PDF
The influence of the solvent on organic reactivity. Part 4. Spectroscopic parameters of Lewis basicity and acidity of hydroxylic solvents. A comprehensive correlation analysis of the log k values for the reactions of diazodiphenylmethane with benzoic acid in aprotic and hydroxylic solvents at 37 C
M. Hanif Aslam Geoffrey Collier and John Shorter
pg 1572; DOI:
10.1039/P29810001572
PDF
The heterogeneous thermal transformation of the yellow to the orange crystalline form of diethyl 2,5-diaminoterephthalate. X-Ray crystal structures of the two forms
Barbara J. Mann Eileen N. Duesler Iain C. Paul and David Y. Curtin
pg 1577; DOI:
10.1039/P29810001577
PDF
The heterogeneous thermal transformation of the orange diethyl NN-diphenyl-2,5-diaminoterephthalate benzene complex to the red solvent-free compound. X-Ray crystal structures of the two forms
Barbara J. Mann Iain C. Paul and David Y. Curtin
pg 1583; DOI:
10.1039/P29810001583
PDF
Ion-molecule reactions in the gas phase. Part 1. Stereospecific nucleophilic substitution of tertiary alcohols by ammonia
J. Bastard D. Do Khac Manh M. Fetizon J. C. Tabet and D. Fraisse
pg 1591; DOI:
10.1039/P29810001591
PDF
Kinetics and mechanisms of the Bamberger rearrangement. Part 4. Rearrangement of sterically hindered phenylhydroxylamines to 4-aminophenols in aqueous sulphuric acid solution
Takaaki Sone Kazuhiro Hamamoto Yoshiyuki Seiji Seiji Shinkai and Osamu Manabe
pg 1596; DOI:
10.1039/P29810001596
PDF
Anodic oxidation of carboxamides. Part 3. The mechanism of anodic cyclization of N-methylcarbanilides
Hidenobu Ohmori Chihiro Ueda Yasuhiro Nobusue Naoko Saitou Tomoko Yokota and Masaichiro Masui
pg 1599; DOI:
10.1039/P29810001599
PDF
The crystal structures of 1,5,12,16,23,26,29,32,35-nonaoxa[13][5.5]orthocyclophane and its complex with rubidium picrate
Ian R. Hanson John D. Owen and Mary R. Truter
pg 1606; DOI:
10.1039/P29810001606
PDF
Selective functionalisation. Part 4. 1H Nuclear magnetic resonance studies of the orientation of aromatic molecules by surfactant micelles
Colin J. Suckling and Alan A. Wilson
pg 1616; DOI:
10.1039/P29810001616
PDF
The crystal structure, absolute configuration, and circular dichroism of (R)-(–)546-8,8-(2-thiatrimethylene)-1,1-binaphthyl
James D. Korp Ivan Bernal Margaret M. Harris and Piyushbhai K. Patel
pg 1621; DOI:
10.1039/P29810001621
PDF
The kinetics and mechanisms of aromatic halogen substitution. Part 35. The directive effect of the benzoyloxy-substituent
Judith M. Brittain Peter B. D. de la Mare and Janet M. Smith
pg 1629; DOI:
10.1039/P29810001629
PDF